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It's a hard toss-up of the Paladin t2 and Shaman t8. Both sets are highly detailed, and truly define both of the classes. I like the new t12 Pally set as well because it sort of brings back the look of the original t2 for Paladins. I'm hoping the Shaman t12 also brings back that shamanistic feel. However as far as favorites go nothing trumps the Pally t2 and the Shammy t8.
I just love the Tier 6 (Rift stalker armor) of the hunter and all the tbc tier in general.But when i saw that tier i said, "I have to start play wow" and that's how i started playing...ironically hunter wasn't neither my 1st/2nd/3rd/4th char but the 5th..and i don't play it cause i hate the focus thing...still 80.
T10 elemental shaman setOne of the first sets I finished. I like the frosty look of the 264 version, and the spirit talbuks coming from the shoulders once in a while.
I LOVED the T5/Arena 2 set for the rogue! They've gotten a little flamboyant with the rogue sets since and personally like the slightly grittier look they went with there.
I would have to also say that the Priest T5 Avatar Raiment/Regalia set was definitely my favourite set. I have been highly disappointed in the looks of the recent tier sets. I play a Holy Priest as my Main, I would love for my gear to also speak volumes on what Class/Spec I play. The wings on the shoulders, the white and cold trimmed and hood, the glow, it is a rather Angelic looking set and says I'm a Priest! Also the black undertone colours of the skirt of the robes and black of the face also complimented the Shadow Priest spec as well.
I would have to go with Warrior Tier 6 because my main is a warrior and it has been my favorite Warrior gear up to now as well as the amount of time and work you had to put in to getting the full set and work harder once Sunwell came out to finish out the set with the boots, bracers, belt.
Corruptor Raiment (warlock T5)i like that because you cant wear a helm like this if you are not warlockhttp://www.wowhead.com/item=30212#same-model-as
Rogue Tier 2. I loved the way the Bloodfang Set, because it had it's own unique look to it. The Hood and Shoulders always looked beastly.
My favorite so far was warrior t10 277 ilvl cause i got to wear it on my warrior and it just felt epic ).
my favourite set is the paladin dungeon set 1. I have many memories of going through the original azeroth dungeons with friends trying for this set. it's the set I've mostly gone after many times on different characters.