I have to go with Dragonstalker. Thanks to only seeing two Giantstalker leggings during weekly MC runs through all of classic, my T2 was the first set I ever completed, and fairly early on at that. As an added reason for the love, I got my first few pieces while it was still a gold recoloring of the pre-re-skinned T0. After being fairly meh'd by the new skin for T1, I started a sketch in one of my more boring lectures of a T0 dwarf, a modified more to what I wished it would have looked like T1 female night elf, and a male night elf in what I hopped the coming T2 skin would look like. Except for the boots and a few minor details elsewhere--and the Chromatic Dragonflight purple scales over one of the other five flights--it came out almost exactly as I had hoped, ensuring its place in that soft spot of my heart.
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The T12 since this is the first one i will really be shooting for.
Teir 9 Because The Armour Looked Differnt based on your faction and made it feel a little bit more unique.
I would have to say Destroyer Battlegear was my favorite armor set. It just gave warriors the intimidating appearance that they deserve.
My favourite tier set is the Hunter tier 4 set as this was the first set I actively tried to get on my hunter main back in TBC. During Vanilla I had just bumbled along not really knowing what I was doing but in the beginning of TBC I found a great guild and with their assistance I learnt what the tier sets were and also how to get them. So for me even though it doesn't look the best of the Hunter gear, and I no longer really play that toon, this will always be my favourite tier.
At the moment i really like the Tier 11 DK gear, mainly because i want my death knight to have it, it looks good, and the stats are just brilliant :)
Druid T4 is my favorite, but that's because it was the only complete tier set I got. Malorne Harness
My favorite is the warlock T6 Raid Set {Malefic Raiment}, I love the look of this set and the cool wings that just pop out when they feel like it. Epic design and wings to boot, how could you go wrong?
In my opinion "Conqueror's Sanctification Regalia" (Conqueror's Sanctification Regalia)was the most awesome set ever.During Ulduar I played a Priest and was very proud to own the complete set.I really loved the art,especially the head piece was great!
My choice goes to the paladin Tier 2. I love the colors and details, is "joyful" while imposing.
Shaman Tier 8 and Tier 5/6 were damn awesome.Winner would have to be Tier 8 though, those chains on the gear man, those chains!