I like the paladin tier 12 the most because it looks so epic!
By far tier 1 hunters Blizz always put the best work into the older stuff nowa days all it is is copy's with different colors... The first Tiers will always the be the best tiers because of originality and the effort they put into making them the best!
My favorite set is the shaman tier 5. One of the few sets not to feature a skirt and you looked like the complete and total master of fir wearing it.
Got many favourite sets, for many classes, but since my main is a paladin, i'd say my favourite one was the 10-man Ulduar one (Aegis one); cuz it was pretty awesome with the colour and the look, it really gave u a sensation of "holyness" :P which a paladin set should have, not like other crap paladin sets, like T1 or T5 :(
The Shaman T5 Cataclysm Harness is sooo epic! I have to collect it!
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Pally T2 Raid Set, the beautiful Judgement Armor. Featured in a lot of WoW concept and fan art and particularly flattering on female Bloodelves. ::Drool::Never again will such an iconic, bad-ass looking, class-suiting set exist :'(
Priest T6 set for sure, the shoulders sell it. Never got my hands on it, but I always coveted those when I saw them running around. http://www.wowwiki.com/Vestments_of_Absolution
Warlock tier five for it's menacing look and feel. Red and black theme, glowy-eyed skulls on spikes, and chains binding the while raiment together work to give the set the appearance that the wearer could reach into your soul and destroy you from within.
Paladin T2, lets just say that's how I imagine paladin looks from old D&D days.
i like the light sworn armor set because it looks awesome
I would have to say either Druid T3 or Warlock T5. The Druid T3 Dreamwalker's Raiment simply had a sleek elegance to it and the spaulders were simply epic. On the same note, the Warlock T5 'Corrupter's Raiment' had a menacing and foreboding aura to it that made it awesome in it's own way, despite it not having all these bright colours and fancy designs on it. Overall those would have to be my favourite sets, though if I had to choose between the two I would probably got for Druid T3.
T10.Because it's sexy.
My favourite set is Nordrassil : Nordrassil HarnessI love those shoulders! So very druid!
By far my favourite is Bloodfang. I know people are constantly licking it's proverbial feet, but back in the day when most people were running around in dungeon blues, when you saw that one guy wearing full Bloodfang with that helm, you knew he was hardcore. I remember the day we first downed Onyxia and I rolled 99 on the helm and won... That was probably the most excited I've ever gotten over a single piece of gear. When I think of rogue, I think of the hood and the glowing eyes peering out from the shadows. Tier 9 would have overtaken it as my favourite had it not been completely ruined by that ridiculous gremlin head.
Rogue T7 Heroes Bonescythe Battlegear. Makes a rogue look like he/she should :)