My favorite Tier set has always been Paladin T2, the Judgement set. I've always loved playing WoW, but ever since I saw someone wearing that set, I knew I wanted to keep playing and start raiding. Making a pally of my own and getting a whole Judgement set for it has been my first and original goal I've ever had on this game, even before wanting to be level 60 >.<
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Druid Tier 6, Thunderheart, is my favorite. It just look awesome and show how a real druid should look. The feathers, the colors, the eagle heads on shoulders and head piece, everything is just amazing.
Personally, my favorite tier set is the T2 paladin set.To me, it's an iconic armor. When you see the T2 paladin it just looks amazing. I created a paladin back in the day just for that reason. It inspired me to get the whole set. (But in reality, I only got the helmet from Onyxia XD).
My favorite tier set was mage tier 10. The dragon mask was most awesome and looked great with the rest of the set. Not to mention the awesome four piece bonus, which (speaking as arcane at the time) to me really outshone almost all the other sets of that tier.
T12...the "Snake Plissken" look on hunters just does it for me. B^)
Rogue T2, because I spent so long collecting my full set, enjoyed the content so much, and back in the day of 40-man raids, complete sets were harder to get. Was a challenge to get them, and always felt rewarding to do so. Plus, you looked totally awesome in a day when armor was a lot more bland.
Hunter T11 because murlocs are epic!
My favorite tier set is still Merciless Gladiator's Vestments (Arena season 2 rogue set). To me, it defined what rogue gear should look like - simple, elegant, and lethal all at the same time.
I personally was in love with the Druid T5 set, especially in combination with the Pillar of Ferocity, because it matched the feeling I had when I first started my Night Elf druid and it completely fitted the design and lore of a druid.This is partially because it was the first set I got all 5 pieces of and due the fact that the staff dropped on our first kill of Anetheron back in the day, it is surely one of the tier sets that I will always keep in my bags, just to equip now and then while sitting in Stormwind and reminiscing of the good old days of TBC raiding. /endnostalgia
My favorite tier set would have to be the Paladin Tier two set. The judgement set looked great together, the colors were amazing and the shoulders/helm were awesome. They matched perfectly with Sulfuras and Thunderfury, not that I had either of them, but they still looked amazing with the legendaries that were relevant to the gear. I know people who still farm BWD to try to get all 8/8 of the set.
Warlock t5 was the because of the wing animation on the shoulders...wish all the other tiers could compare
I loved http://www.wowhead.com/itemset=387#. because I felt like a battle-mage!