Purely on looks, Judgement set. Followed closely by Priest t5/6. the ENTIRE t8 sets looked awesome, as did a number of the t10 sets.I've loved the Judgement set since vanilla, even though I play horde, and did so then. Priest t5/6 just fit so well with the class.
Rogue tier 5 deathmantle that with a teebus blazeing longsword and spellfire long sword to look like a sith
Druid T1
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Druid Tier 3, as this set was without a doubt the most difficult to complete. Competing against a full raid group of 40 people for tier tokens led to an unholy grind that still leaves me fetal in the corner whenever I have flashbacks to it. But hey, at least Naxx was a blast. Back then.
Simple.. Paladin tier 2 - Judgement Was 1 of the first on my realm to have the full set back in the old days, and barely anyone else had any
Hunter T3 with AQ40 weapons, win.
Shaman tier 10.5 was my favorite. I loved the frozen look and was always very disappointed with Lord Marrowgar when the matching shield never dropped v.v
For my paladin, my favorite was Tier6. Being a horde, I didn't have access to Tier3. But in BC, lets be honest, 4 was blah, 5 looked horrid, so 6 was and still remains my favorite for paladins
My favorite tier set is T10 warrior, because I loved the shoulder pads and helmet.
I really loved the tier 10 sets for all classes but mainly for death knights, especially the Frost one because of the design of the skull face on the gloves and the belt and the shoulders. The glowing effects really made it look intimidating and what set you got coincided with your spec . However, all the designs for the tier 10 sets were amazing and stood out from all the other gear you can obtain.
Of course its the warlock t6 ! Have a big red awesome wings (who dont like big things?) the skull helm (I LUVVV Skull) and so $%^&in badass :D thats why i like warlocks !, but since wotlk i didnt see any good tiers=/ t2 were soo beautiful too , but unfortunately i didnt play vanila wow =/ , but i hope t12 will be good (HOPE)
Paladin Tier 2. The holy plate dress of the modern tiers may be annoying, but ion Judgment, it looks amazing.Especially back in the day, it always felt the detail on the armor was perfect. There have been other et I have liked, but nothing matches the first love.