I loved the Hunter tier 5, Rift Stalker Armor, not for how it looked, but for the what it did. It was one of the only sets of armor that had a purpose after Burning Crusade. Back then, i remember healing being much more of a chore than it is now, and the armor set alleviated healing greatly. Seriously, it was just "set it, and forget it". Ah, the olden days, where hunter had mana, bullets and worries. This set just reminds of different times.
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A lot of people are saying Warlock T6, Malefic Raiment. And I wholeheartedly agree. Just too bad I wasn't playing back then. I would have kept the entire set to wear around in Org.
Druid T1 is my absolute favorite. It just seems the most in line with the character, the antlers on the helm, and the leaves/twigs on the shoulders. Absolutely lovely.
Rogue T10 for me. Just looking at it made me feel like a badass dealer of death, which got me pumped up for raids.
I have to admit that as a shadow priest I always want some sort of hood to be all dark and mysterious (lovely cliche right?) and tier 10 was the one that did it for me, especially the 25man hc version of tier 10, my favourite "colours" combined with a smooth design made me squee.
The best Tier for me? simple, the last on pally... why? because i need a new pc ;-)
Mage tier 11. It just looks pretty awesome with the skull helm and everything. I have to say, the Paladins look nice too on Tier 4.
I think my favorite was the Tier 2 Priest, the Transcendent set. My Priest was my first character (and I leveled her as Holy. In Vanilla.) and while the first set I ever collected was the Devout, it was the Transcendent that REALLY made me want to raid and earn that gear. Sadly, I never did. I just didn't have the time to devote to hardcore raiding back then. Still don't, but at least tier sets are a bit easier to come by now than they were back in the day.
i have to say hunters t6 the eyes made it look so awesome "i can see you" it fits the role of the hunterGronnstalker's Armor
Without a doubt, warlock tier 5, it just screams manipulator of dark magic. You see that coming at you and you just know you're about to get rocked. The day that the arena look-alike set was accidentally free, I was so excited to do nothing but stare at the sexiness of that set on my lock. It doesn't look gimmicky or cartoonish like other tiers did and it brought the warlock vibe of Dreadmist to a new, much darker level. It was one that looked great on any race. I absolutely love the warlock tier 5 and wish that all other sets try to reach the bar that was set with that one.
I think T2 raid set from Paladins are the best ever made.Paladins looks like a REAL paladin with that. Today ones are nice too, but that one... that one is the one that paladins always need to get, even in lvl 85.
Justicar Regalia (Paladin Tier 2) is still the most beautiful tier set in Wow.
Have to be Priest T10. I've been in a casual guild for my WoW career, and ICC was the first time I really started in on hard modes, and tackling content that was considered difficult for the masses. So it's the first set that I really feel like I earned.